Optimized GC-MS method to simultaneously quantify acetylated aldose, ketose, and alditol for plant tissues based on derivatization in a methyl sulfoxide/1-methylimidazole system.
Identifieur interne : 002566 ( Main/Exploration ); précédent : 002565; suivant : 002567Optimized GC-MS method to simultaneously quantify acetylated aldose, ketose, and alditol for plant tissues based on derivatization in a methyl sulfoxide/1-methylimidazole system.
Auteurs : Ke Li [République populaire de Chine] ; Shichang Liu ; Yupeng Tan ; Nan Chao ; Xiaoming Tian ; Liwang Qi ; William A. Powell ; Xiangning Jiang ; Ying GaiSource :
- Journal of agricultural and food chemistry [ 1520-5118 ] ; 2013.
Descripteurs français
- KwdFr :
- Acétylation (MeSH), Anhydrides acétiques (composition chimique), Chromatographie gazeuse-spectrométrie de masse (méthodes), Cétoses (sucres) (analyse), Diméthylsulfoxyde (composition chimique), Ginkgo biloba (composition chimique), Glucose (analyse), Imidazoles (composition chimique), Limite de détection (MeSH), Oses (composition chimique), Polyols (analyse), Populus (composition chimique).
- MESH :
- analyse : Cétoses (sucres), Glucose, Polyols.
- composition chimique : Anhydrides acétiques, Diméthylsulfoxyde, Ginkgo biloba, Imidazoles, Oses, Populus.
- méthodes : Chromatographie gazeuse-spectrométrie de masse.
- Acétylation, Limite de détection.
English descriptors
- KwdEn :
- Acetic Anhydrides (chemistry), Acetylation (MeSH), Dimethyl Sulfoxide (chemistry), Gas Chromatography-Mass Spectrometry (methods), Ginkgo biloba (chemistry), Glucose (analysis), Imidazoles (chemistry), Ketoses (analysis), Limit of Detection (MeSH), Monosaccharides (chemistry), Populus (chemistry), Sugar Alcohols (analysis).
- MESH :
- chemical , analysis : Glucose, Ketoses, Sugar Alcohols.
- chemical , chemistry : Acetic Anhydrides, Dimethyl Sulfoxide, Imidazoles, Monosaccharides.
- chemistry : Ginkgo biloba, Populus.
- methods : Gas Chromatography-Mass Spectrometry.
- Acetylation, Limit of Detection.
Abstract
The isomers of monosaccharide always produce multiple chromatographic peaks as volatile derivatives during gas chromatography, which may result in the overlapping of different sugar peaks. Whereas reduction and oximation of sugar carbonyl groups for GC analysis do eliminate many isomer derivatives, the approaches create new problems. One ketose can yield two peaks by oximation, and different aldoses and ketoses can yield the same alditol upon reduction, leading to the inability to detect some important monosaccharides. This paper reports an optimal method that yields a single peak per sugar by acetylation directly. By using a methyl sulfoxide (Me2SO)/1-methylimidazole (1-MeIm) system, the carbohydrates in acetic anhydride (Ac2O) esterification reactions were solubilized, and the oxidation that normally occurs was inhibited. The results demonstrate that acetylated derivatives of 23 saccharides had unique peaks, which indicates aldose, ketose, and alditol can be determined simultaneously by GC-MS.
DOI: 10.1021/jf3053862
PubMed: 23541076
Affiliations:
Links toward previous steps (curation, corpus...)
Le document en format XML
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Powell</name></author><author><name sortKey="Jiang, Xiangning" sort="Jiang, Xiangning" uniqKey="Jiang X" first="Xiangning" last="Jiang">Xiangning Jiang</name></author><author><name sortKey="Gai, Ying" sort="Gai, Ying" uniqKey="Gai Y" first="Ying" last="Gai">Ying Gai</name></author></titleStmt><publicationStmt><idno type="wicri:source">PubMed</idno><date when="2013">2013</date><idno type="RBID">pubmed:23541076</idno><idno type="pmid">23541076</idno><idno type="doi">10.1021/jf3053862</idno><idno type="wicri:Area/Main/Corpus">002651</idno><idno type="wicri:explorRef" wicri:stream="Main" wicri:step="Corpus" wicri:corpus="PubMed">002651</idno><idno type="wicri:Area/Main/Curation">002651</idno><idno type="wicri:explorRef" wicri:stream="Main" wicri:step="Curation">002651</idno><idno type="wicri:Area/Main/Exploration">002651</idno></publicationStmt><sourceDesc><biblStruct><analytic><title xml:lang="en">Optimized GC-MS method to simultaneously quantify acetylated aldose, ketose, and alditol for plant tissues based on derivatization in a methyl sulfoxide/1-methylimidazole system.</title><author><name sortKey="Li, Ke" sort="Li, Ke" uniqKey="Li K" first="Ke" last="Li">Ke Li</name><affiliation wicri:level="1"><nlm:affiliation>College of Biological Sciences and Biotechnology, Beijing Forestry University , Beijing 100083, People's Republic of China.</nlm:affiliation><country xml:lang="fr">République populaire de Chine</country><wicri:regionArea>College of Biological Sciences and Biotechnology, Beijing Forestry University , Beijing 100083</wicri:regionArea><placeName><settlement type="city">Pékin</settlement></placeName></affiliation></author><author><name sortKey="Liu, Shichang" sort="Liu, Shichang" uniqKey="Liu S" first="Shichang" last="Liu">Shichang Liu</name></author><author><name sortKey="Tan, Yupeng" sort="Tan, Yupeng" uniqKey="Tan Y" first="Yupeng" last="Tan">Yupeng Tan</name></author><author><name sortKey="Chao, Nan" sort="Chao, Nan" uniqKey="Chao N" first="Nan" last="Chao">Nan Chao</name></author><author><name sortKey="Tian, Xiaoming" sort="Tian, Xiaoming" uniqKey="Tian X" first="Xiaoming" last="Tian">Xiaoming Tian</name></author><author><name sortKey="Qi, Liwang" sort="Qi, Liwang" uniqKey="Qi L" first="Liwang" last="Qi">Liwang Qi</name></author><author><name sortKey="Powell, William A" sort="Powell, William A" uniqKey="Powell W" first="William A" last="Powell">William A. Powell</name></author><author><name sortKey="Jiang, Xiangning" sort="Jiang, Xiangning" uniqKey="Jiang X" first="Xiangning" last="Jiang">Xiangning Jiang</name></author><author><name sortKey="Gai, Ying" sort="Gai, Ying" uniqKey="Gai Y" first="Ying" last="Gai">Ying Gai</name></author></analytic><series><title level="j">Journal of agricultural and food chemistry</title><idno type="eISSN">1520-5118</idno><imprint><date when="2013" type="published">2013</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Acetic Anhydrides (chemistry)</term><term>Acetylation (MeSH)</term><term>Dimethyl Sulfoxide (chemistry)</term><term>Gas Chromatography-Mass Spectrometry (methods)</term><term>Ginkgo biloba (chemistry)</term><term>Glucose (analysis)</term><term>Imidazoles (chemistry)</term><term>Ketoses (analysis)</term><term>Limit of Detection (MeSH)</term><term>Monosaccharides (chemistry)</term><term>Populus (chemistry)</term><term>Sugar Alcohols (analysis)</term></keywords><keywords scheme="KwdFr" xml:lang="fr"><term>Acétylation (MeSH)</term><term>Anhydrides acétiques (composition chimique)</term><term>Chromatographie gazeuse-spectrométrie de masse (méthodes)</term><term>Cétoses (sucres) (analyse)</term><term>Diméthylsulfoxyde (composition chimique)</term><term>Ginkgo biloba (composition chimique)</term><term>Glucose (analyse)</term><term>Imidazoles (composition chimique)</term><term>Limite de détection (MeSH)</term><term>Oses (composition chimique)</term><term>Polyols (analyse)</term><term>Populus (composition chimique)</term></keywords><keywords scheme="MESH" type="chemical" qualifier="analysis" xml:lang="en"><term>Glucose</term><term>Ketoses</term><term>Sugar Alcohols</term></keywords><keywords scheme="MESH" type="chemical" qualifier="chemistry" xml:lang="en"><term>Acetic Anhydrides</term><term>Dimethyl Sulfoxide</term><term>Imidazoles</term><term>Monosaccharides</term></keywords><keywords scheme="MESH" qualifier="analyse" xml:lang="fr"><term>Cétoses (sucres)</term><term>Glucose</term><term>Polyols</term></keywords><keywords scheme="MESH" qualifier="chemistry" xml:lang="en"><term>Ginkgo biloba</term><term>Populus</term></keywords><keywords scheme="MESH" qualifier="composition chimique" xml:lang="fr"><term>Anhydrides acétiques</term><term>Diméthylsulfoxyde</term><term>Ginkgo biloba</term><term>Imidazoles</term><term>Oses</term><term>Populus</term></keywords><keywords scheme="MESH" qualifier="methods" xml:lang="en"><term>Gas Chromatography-Mass Spectrometry</term></keywords><keywords scheme="MESH" qualifier="méthodes" xml:lang="fr"><term>Chromatographie gazeuse-spectrométrie de masse</term></keywords><keywords scheme="MESH" xml:lang="en"><term>Acetylation</term><term>Limit of Detection</term></keywords><keywords scheme="MESH" xml:lang="fr"><term>Acétylation</term><term>Limite de détection</term></keywords></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The isomers of monosaccharide always produce multiple chromatographic peaks as volatile derivatives during gas chromatography, which may result in the overlapping of different sugar peaks. Whereas reduction and oximation of sugar carbonyl groups for GC analysis do eliminate many isomer derivatives, the approaches create new problems. One ketose can yield two peaks by oximation, and different aldoses and ketoses can yield the same alditol upon reduction, leading to the inability to detect some important monosaccharides. This paper reports an optimal method that yields a single peak per sugar by acetylation directly. By using a methyl sulfoxide (Me2SO)/1-methylimidazole (1-MeIm) system, the carbohydrates in acetic anhydride (Ac2O) esterification reactions were solubilized, and the oxidation that normally occurs was inhibited. The results demonstrate that acetylated derivatives of 23 saccharides had unique peaks, which indicates aldose, ketose, and alditol can be determined simultaneously by GC-MS. </div></front></TEI><pubmed><MedlineCitation Status="MEDLINE" Owner="NLM"><PMID Version="1">23541076</PMID><DateCompleted><Year>2014</Year><Month>07</Month><Day>07</Day></DateCompleted><DateRevised><Year>2013</Year><Month>11</Month><Day>25</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1520-5118</ISSN><JournalIssue CitedMedium="Internet"><Volume>61</Volume><Issue>17</Issue><PubDate><Year>2013</Year><Month>May</Month><Day>01</Day></PubDate></JournalIssue><Title>Journal of agricultural and food chemistry</Title><ISOAbbreviation>J Agric Food Chem</ISOAbbreviation></Journal><ArticleTitle>Optimized GC-MS method to simultaneously quantify acetylated aldose, ketose, and alditol for plant tissues based on derivatization in a methyl sulfoxide/1-methylimidazole system.</ArticleTitle><Pagination><MedlinePgn>4011-8</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1021/jf3053862</ELocationID><Abstract><AbstractText>The isomers of monosaccharide always produce multiple chromatographic peaks as volatile derivatives during gas chromatography, which may result in the overlapping of different sugar peaks. Whereas reduction and oximation of sugar carbonyl groups for GC analysis do eliminate many isomer derivatives, the approaches create new problems. One ketose can yield two peaks by oximation, and different aldoses and ketoses can yield the same alditol upon reduction, leading to the inability to detect some important monosaccharides. This paper reports an optimal method that yields a single peak per sugar by acetylation directly. By using a methyl sulfoxide (Me2SO)/1-methylimidazole (1-MeIm) system, the carbohydrates in acetic anhydride (Ac2O) esterification reactions were solubilized, and the oxidation that normally occurs was inhibited. The results demonstrate that acetylated derivatives of 23 saccharides had unique peaks, which indicates aldose, ketose, and alditol can be determined simultaneously by GC-MS. </AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Li</LastName><ForeName>Ke</ForeName><Initials>K</Initials><AffiliationInfo><Affiliation>College of Biological Sciences and Biotechnology, Beijing Forestry University , Beijing 100083, People's Republic of China.</Affiliation></AffiliationInfo></Author><Author ValidYN="Y"><LastName>Liu</LastName><ForeName>Shichang</ForeName><Initials>S</Initials></Author><Author ValidYN="Y"><LastName>Tan</LastName><ForeName>Yupeng</ForeName><Initials>Y</Initials></Author><Author ValidYN="Y"><LastName>Chao</LastName><ForeName>Nan</ForeName><Initials>N</Initials></Author><Author ValidYN="Y"><LastName>Tian</LastName><ForeName>Xiaoming</ForeName><Initials>X</Initials></Author><Author ValidYN="Y"><LastName>Qi</LastName><ForeName>Liwang</ForeName><Initials>L</Initials></Author><Author ValidYN="Y"><LastName>Powell</LastName><ForeName>William A</ForeName><Initials>WA</Initials></Author><Author ValidYN="Y"><LastName>Jiang</LastName><ForeName>Xiangning</ForeName><Initials>X</Initials></Author><Author ValidYN="Y"><LastName>Gai</LastName><ForeName>Ying</ForeName><Initials>Y</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType UI="D016428">Journal Article</PublicationType><PublicationType UI="D013485">Research Support, Non-U.S. Gov't</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2013</Year><Month>04</Month><Day>17</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>J Agric Food Chem</MedlineTA><NlmUniqueID>0374755</NlmUniqueID><ISSNLinking>0021-8561</ISSNLinking></MedlineJournalInfo><ChemicalList><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D000089">Acetic Anhydrides</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D007093">Imidazoles</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D007661">Ketoses</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D009005">Monosaccharides</NameOfSubstance></Chemical><Chemical><RegistryNumber>0</RegistryNumber><NameOfSubstance UI="D013402">Sugar Alcohols</NameOfSubstance></Chemical><Chemical><RegistryNumber>2E48G1QI9Q</RegistryNumber><NameOfSubstance UI="C031800">acetic anhydride</NameOfSubstance></Chemical><Chemical><RegistryNumber>IY9XDZ35W2</RegistryNumber><NameOfSubstance UI="D005947">Glucose</NameOfSubstance></Chemical><Chemical><RegistryNumber>P4617QS63Y</RegistryNumber><NameOfSubstance UI="C018100">1-methylimidazole</NameOfSubstance></Chemical><Chemical><RegistryNumber>YOW8V9698H</RegistryNumber><NameOfSubstance UI="D004121">Dimethyl Sulfoxide</NameOfSubstance></Chemical></ChemicalList><CitationSubset>IM</CitationSubset><MeshHeadingList><MeshHeading><DescriptorName UI="D000089" MajorTopicYN="N">Acetic Anhydrides</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D000107" MajorTopicYN="N">Acetylation</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D004121" MajorTopicYN="N">Dimethyl Sulfoxide</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D008401" MajorTopicYN="N">Gas Chromatography-Mass Spectrometry</DescriptorName><QualifierName UI="Q000379" MajorTopicYN="Y">methods</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D020441" MajorTopicYN="N">Ginkgo biloba</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D005947" MajorTopicYN="N">Glucose</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="N">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D007093" MajorTopicYN="N">Imidazoles</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D007661" MajorTopicYN="N">Ketoses</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="Y">analysis</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D057230" MajorTopicYN="N">Limit of Detection</DescriptorName></MeshHeading><MeshHeading><DescriptorName UI="D009005" MajorTopicYN="N">Monosaccharides</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="N">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D032107" MajorTopicYN="N">Populus</DescriptorName><QualifierName UI="Q000737" MajorTopicYN="Y">chemistry</QualifierName></MeshHeading><MeshHeading><DescriptorName UI="D013402" MajorTopicYN="N">Sugar Alcohols</DescriptorName><QualifierName UI="Q000032" MajorTopicYN="Y">analysis</QualifierName></MeshHeading></MeshHeadingList></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="entrez"><Year>2013</Year><Month>4</Month><Day>2</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2013</Year><Month>4</Month><Day>2</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2014</Year><Month>7</Month><Day>8</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="pubmed">23541076</ArticleId><ArticleId IdType="doi">10.1021/jf3053862</ArticleId></ArticleIdList></PubmedData></pubmed><affiliations><list><country><li>République populaire de Chine</li></country><settlement><li>Pékin</li></settlement></list><tree><noCountry><name sortKey="Chao, Nan" sort="Chao, Nan" uniqKey="Chao N" first="Nan" last="Chao">Nan Chao</name><name sortKey="Gai, Ying" sort="Gai, Ying" uniqKey="Gai Y" first="Ying" last="Gai">Ying Gai</name><name sortKey="Jiang, Xiangning" sort="Jiang, Xiangning" uniqKey="Jiang X" first="Xiangning" last="Jiang">Xiangning Jiang</name><name sortKey="Liu, Shichang" sort="Liu, Shichang" uniqKey="Liu S" first="Shichang" last="Liu">Shichang Liu</name><name sortKey="Powell, William A" sort="Powell, William A" uniqKey="Powell W" first="William A" last="Powell">William A. Powell</name><name sortKey="Qi, Liwang" sort="Qi, Liwang" uniqKey="Qi L" first="Liwang" last="Qi">Liwang Qi</name><name sortKey="Tan, Yupeng" sort="Tan, Yupeng" uniqKey="Tan Y" first="Yupeng" last="Tan">Yupeng Tan</name><name sortKey="Tian, Xiaoming" sort="Tian, Xiaoming" uniqKey="Tian X" first="Xiaoming" last="Tian">Xiaoming Tian</name></noCountry><country name="République populaire de Chine"><noRegion><name sortKey="Li, Ke" sort="Li, Ke" uniqKey="Li K" first="Ke" last="Li">Ke Li</name></noRegion></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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